Mesoporous 2D covalent organic frameworks based on shape-persistent arylene-ethynylene macrocycles† †Electronic supplementary information (ESI) available: Experimental procedures, TGA, FT-IR, PXRD and NMR spectra of compounds. See DOI: 10.1039/c5sc00894h

Regulating the topology of 2D covalent organic frameworks by the rational introduction of substituents† †Electronic supplementary information (ESI) available: Procedure for the preparation of the COFs, IR spectra, solid-state 13C NMR, SEM images, TGA traces, PXRD profiles and simulations, fractional atomic coordinates, and BET plots. See DOI: 10.1039/c6sc05673c Click here for additional data file.

The topology of a covalent organic framework (COF) is generally believed to be dictated by the symmetries of the monomers used for the condensation reaction. In this context, the use of monomers with different symmetries is usually required to afford COFs with different topologies. Herein, we report a conceptual strategy to regulate the topology of 2D COFs by introducing alkyl substituents into...

Bond breakage under pressure in a metal organic framework† †Electronic supplementary information (ESI) available: PXRD, SEM, FT-IR, fitting results of R-space EXAFS of UiO-66 nanocrystals. See DOI: 10.1039/c7sc03786d

Light responsive metal–organic frameworks as controllable CO-releasing cell culture substrates† †Electronic supplementary information (ESI) available: PXRD, XRF and EDX quantification, electron microscopy, N2 adsorption isotherms, FTIR and UV-Vis spectroscopic characterization and TGA data. See DOI: 10.1039/c6sc04824b Click here for additional data file.

Versatile rare earth hexanuclear clusters for the design and synthesis of highly-connected ftw-MOFs† †Electronic supplementary information (ESI) available: Materials and methods, synthesis of ligands, NMR spectra, synthesis of MOFs, additional structural figures, PXRD, TGA, low and high pressure gas adsorption isotherms, Qst analysis and IAST calculation. CCDC 1050062–1050064. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00614g

Functional Materials Design, Discovery & Advanced Membranes & Porous Materials C Engineering, King Abdullah University of S 23955-6900, Kingdom of Saudi Arabia. E-m Department of Chemistry, University of S Tampa, Florida 33620, USA † Electronic supplementary information ( synthesis of ligands, NMR spectra, syn gures, PXRD, TGA, low and high pre analysis and IAST calculation. CCD crystallograph...

Two exfoliation approaches for organic layered compounds: hydrophilic and hydrophobic polydiacetylene nanosheets† †Electronic supplementary information (ESI) available: Experimental procedure, UV-Vis spectra, FT-IR spectra, XRD profiles and AFM images. See DOI: 10.1039/c6sc03350d Click here for additional data file.

Electronic Supplementary Information (ESI) Two exfoliation approaches for organic layered compounds: hydrophilic and hydrophobic polydiacetylene nanosheets Yukiko Ishijima,+ Mamoru Okaniwa,+ Yuya Oaki,* Hiroaki Imai Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-141 Hiyoshi, Kohoku-ku, Yokohama 223-8522, Japan. E-mail: [email protected] +These aut...